𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Rate-limiting deprotonation in tetrahedral intermediate breakdown

✍ Scribed by McClelland, Robert A.


Book ID
126924328
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
638 KB
Volume
106
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Hydrolytic resolution of (R,S)-2-hydroxy
✍ Pei-Yun Wang; Teh-Liang Chen; Shau-Wei Tsai; Wolfgang Kroutil πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 179 KB

## Abstract A thermally stable esterase (SNSM‐87) from __Klebsiella oxytoca__ is explored as an enantioselective biocatalyst for the hydrolytic resolution of (__R,S__)‐2‐hydroxycarboxylic acid esters in biphasic media, where the best methyl esters possessing the highest enantioselectivity and react

Hydrolysis of Thiamin: Evidence for Rate
✍ M.W. Washabaugh; C.C. Yang; A.D. Hollenbach; P. Chen πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 988 KB

Rate constants in the \(\mathrm{pH}\) range 3-9 for formation of the enethiolate product upon hydrolysis of \(N\left(1^{\prime}\right)\)-unprotonated ("free") thiamin (1a), \(N\left(1^{\prime}\right)\)-methylthiamin (3), oxythiamine (4), and several 3-substituted-4-methylhiazolium ions in oxygen-con

Effects of N-alkyl substitution on the f
✍ A.C. Knipe; N. Sridhar; J. Lound-Keast πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 French βš– 180 KB

General base catalysis, and N-alkyl group dependence, of the title rearrangement (which approaches a rate limit at high base concentration) has been interpreted: We recently reported (1) that kinetic studies of intramolecular nucleophilic aromatic displacement of alkoxide ion by the amino group in 2