✦ LIBER ✦
Rate enhancing multi-site interactions in ester hydrolysis catalyzed by Cu2+ complexes of surfactant imidazole ligands in non-ionic micelles
✍ Scribed by Kenji Ogino; Kazuyoshi Nishi; Hiroaki Yamamoto; Toshiharu Yoshida; Waichiro Tagaki
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- French
- Weight
- 259 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The Cu2+ complexes of sutfactant imidazole ligands, having a hydroxyl and a cationic or an anionic polar head groups, were found to be highly active catalysts for the hydrolysis of pcarboxyphenyl picolinate, when the reaction is conducted under micellar conditions. The multisite interactions in the formation of a reactive ternary complex appears to be important for the rate enhancement in non-ionic PGLE micelles.