The rate constants for the quenching of O,('Ag) with carbon disulfide, dimethyl sulfide, dimethyl disulfide, diallyl disulfide, ethyl mercaptan, and thiophene have been determined in a discharge flow system in the absence of oxygen atoms. The rate constants are found to be (6.5 2 0.6) x lo4, (1.8 2
Rate constants of O2(1Δg)
✍ Scribed by Nalini Raja; P. K. Arora; J. P. S. Chatha
- Publisher
- John Wiley and Sons
- Year
- 1986
- Tongue
- English
- Weight
- 363 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0538-8066
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✦ Synopsis
The rate constants of OY('As) with aliphatic alcohols, terpenes, unsaturated hydrocarbons, chlorinated hydrocarbons, oxygen, and diamines have been studied in the presence of NO,. The rate constants for oxygen, 1.2-ethane diamine, and 1,2-propane diamine are (9.9 ? 0.4) x lo2, (8.7 t 0.7) x lo4, and (1.4 -C 0.3) x 10' l/mol/s, respectively. The rate constants for all other compounds are less than the oxygen rate constant.
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