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Rate constants of nonradiative intersystem crossing transitionS1(ππ*) ⇝T1(ππ*) in molecules of aromatic compounds with heteroatoms

✍ Scribed by E. A. Gastilovich; N. V. Korol’kova; V. G. Klimenko

Book ID
110176336
Publisher
SP MAIK Nauka/Interperiodica
Year
2010
Tongue
English
Weight
416 KB
Volume
109
Category
Article
ISSN
0030-400X

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A comparison of the rate constants for intersystem crossing via S1(π,π*) T(π,π*) and S1(n,π*) T(π,π*) paths
✍ H. Dewey; S.G. Hadley 📂 Article 📅 1971 🏛 Elsevier Science 🌐 English ⚖ 291 KB

The rate constants for S1 -T intersystem crossing have been deWmined for rigid glass solutions of phenant!!ne and 9,lOdiazaphenanthrene at the temperature of boiling nitroger;. For phenanthrene intersystem crossing path is Sl(n,n\*) -T(~.z\*) where kiscw~ found to be (4.8 + 1) X 106.sec:1. For 9,Khi