## Abstract The relative rate technique has been used to determine the rate constants for the reactions Cl + CH~3~OCHCl~2~ โ products and Cl + CH~3~OCH~2~CH~2~Cl โ products. Experiments were carried out at 298 ยฑ 2 K and atmospheric pressure using nitrogen as the bath gas. The decay rates of the org
Rate constants for the reaction of atomic chlorine with dimethyl peroxide from 220 to 330 K
โ Scribed by J.V. Michael; D.F. Nava; W.A Payne; L.J. Stief
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 570 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract The rate constant for the reaction of Br + O~3~ โ BrO + O~2~ has been measured at four temperatures from 234 to 360 K by the technique of discharge flow coupled with resonanceโfluorescence detection of bromine atoms. The measured rate constants obey the Arrhenius expression __k__ = (9.4
T h e rate constant for the reaction of ground-state oxygen atoms with methanol has been determined between 297 and 544 K by a phase-shift technique using mercury photosensitized decomposition of N20 to generate oxygen atoms. T h e relative oxygen atom concentration was monitored by the chemilumines
## Abstract The rate constant of the reaction Cl + CH~3~OH (__k__~1~) has been measured in 500โ950 Torr of N~2~ over the temperature range 291โ475 K. The rate constant determination was carried out using the relative rate technique with C~2~H~6~ as the reference compound. Experiments were performed
The pulsed laser photolysis-resonance fluorescence technique has been used to determine the absolute rate coefficient for the Cl atom reaction with a series of ketones, at room temperature (298 ฯฎ 2) K and in the pressure range 15-60 Torr. The rate coefficients obtained (in units of cm 3 molecule ฯช1
## Abstract Using the standard, low pressure, dischargeโflow technique, with resonance fluorescence in the vacuum ultraviolet to observe Cl atoms, rate constants have been determined for the reaction of Cl atoms with O~3~ at temperatures down to 184 K. The measured rate constants for 298โ184 K fit