## Abstract Using a relative rate method, rate constants for the gas phase reactions of O~3~ with 1‐ and 3‐methylcyclopentene, 1‐, 3‐, and 4‐methylcyclohexene, 1‐methylcycloheptene, __cis__‐cyclooctene, 1‐ and 3‐methylcyclooctene, 1,3‐ and 1,5‐cyclooctadiene, and 1,3,5,7‐cyclooctatetraene have been
Rate constants for the gas-phase reactions of O3 with a series of monoterpenes and related compounds at 296 ± 2 K
✍ Scribed by Roger Atkinson; David Hasegawa; Sara M. Aschmann
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- English
- Weight
- 871 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0538-8066
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✦ Synopsis
Rate constants for the gas-phase reactions of O3 with a series of monoterpenes and related compounds have been determined at 296 2 2 K and 740 torr total pressure of air or 0 2 using a combination of absolute and relative rate techniques. Good agreement between the absolute and relative rate data was observed, and the rate constants obtained (in units of cm3 molecule-'
📜 SIMILAR VOLUMES
The kinetics of the gas-phase reactions of 0 3 with a series of alkenes have been investigated at atmospheric pressure (ca. 740 torr) of air and 296 2 2 K, using a relative rate method in the presence of sufficient n-octane to scavenge any OH radicals generated in these reactions. Relative to k(Os +
## Abstract Rate constants for the gas‐phase reactions of O~3~ with the carbonyls acrolein, crotonaldehyde, methacrolein, methylvinylketone, 3‐penten‐2‐one, 2‐cyclohexen‐1‐one, acetaldehyde, and methylglyoxal have been determined at 296 ± 2 K. The rate constants ranged from <6 × 10^−21^ cm^3^ molec
## Abstract Rate constants for the gas‐phase reactions of O~3~ with ethene, propene, 1‐hexene, 1‐heptene, styrene, __o__‐, __m__‐, and __p__‐cresol, __o__‐ and __m__‐xylene, benzylchloride, acrylonitrile, and trichloroethene have been determined at 296 ± 2 K. The rate constants ranged from <5 × 10^
Rate constants for the gas-phase reactions of 0 3 with the sesquiterpenes a-cedrene, a-copaene, P-caryophyllene, a-humulene, and longifolene, and with the monoterpenes limonene, terpinolene, a-phellandrene, and a-terpinene, have been measured using a relative rate technique at 296 5 2 K and atmosphe
The kinetics of the gas-phase reactions of 0 3 with a series of alkenes and two a , p-unsaturated ketones have been investigated at atmospheric pressure (ca. 740 torr) of air and 296 f 2 K, using a relative rate method in the presence of sufficient cyclohexane to scavenge OH radicals generated in th