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Rate constants for reactions in viscous media: correlation between the viscosity of the solvent and the rate constant of the diffusion-controlled reactions

✍ Scribed by Olea, Andres F.; Thomas, J. K.


Book ID
120360916
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
910 KB
Volume
110
Category
Article
ISSN
0002-7863

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Rate constants for the bimolecular self-
✍ H. Schuh; H. Fischer πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 English βš– 775 KB

## Abstract Rate constants for the self‐reaction of __tert__butyl radicals in six __n__alkanes are determined as functions of temperature by kinetic electron‐spin resonance spectroscopy and from rates of product formation. They are well described by a Smoluchowski–Stokes–Einstein treatment includin