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Rate Constants and H Atom Branching Ratios of the Gas-Phase Reactions of Methylidyne CH(X 2 Π) Radical with a Series of Alkanes

✍ Scribed by Loison, Jean-Christophe; Bergeat, Astrid; Caralp, Françoise; Hannachi, Yacine


Book ID
127347123
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
103 KB
Volume
110
Category
Article
ISSN
1089-5639

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Rate constants for the gas-phase reactio
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## Abstract Relative rate constants for the reaction of OH radicals with a series of ketones have been determined at 299 ± 2 K, using methyl nitrite photolysis in air as a source of hydroxyl radicals. Using a rate constant for the reaction of OH radicals with cyclohexane of 7.57 × 10^−12^ cm^3^ mol

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Using a relative rate method, rate constants have been determined at 296 5 2 K for the gas-phase reactions of the OH radical with toluene, the xylenes, and the trimethylbenzenes. Using the recommended literature rate constant for the reaction of OH radicals with propene of (2.66 2 0.40) x lo-" cm3 m