Rate Constants and Branching Ratios for the Reactions of Selected Atmospheric Primary Cations with n -Octane and Isooctane (2,2,4-Trimethylpentane)
β Scribed by Arnold, Susan T.; Viggiano, A. A.; Morris, Robert A.
- Book ID
- 126865617
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 250 KB
- Volume
- 101
- Category
- Article
- ISSN
- 1089-5639
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The title compounds were selected to test the current predictions of OH reaction rate constants The reactions are studied employing flash photolysis/resonance fluorescence in 130 rnbar He at room temperature and up to 420 K. Experimental difficulties were encountered due to the polar and hygroscopic
## Abstract Kinetic data for aqueousβphase reactions of sulfate anion radicals (SO) with perfluorocarboxylates (C~__n__~F~2__n__+1~C(O)O^β^) are needed to evaluate removal and transformation processes of C~__n__~F~2__n__+1~C(O)O^β^ species in the environment, but rate constants for the reactions of