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Rate Coefficients for the Gas Phase Reactions of CF 3 CH 2 F (HFC-134a) with Chlorine and Fluorine Atoms: Experimental and ab Initio Theoretical Studies

✍ Scribed by Louis, Florent; Talhaoui, Abdelmonaem; Sawerysyn, Jean-Pierre; Rayez, Marie-Thérèse; Rayez, Jean-Claude

Book ID
127295606
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
146 KB
Volume
101
Category
Article
ISSN
1089-5639

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## Abstract Relative rate experiments using UV photolysis of F~2~ or Cl~2~ have been used to determine rate constant ratios for several hydrofluorocarbon (HFC) reactions with Cl or F atoms and for HFC alkyl radicals with molecular halogens. For mixtures with F~2~ present, dark reactions are, also,