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Rate Coefficients for Reactions of OH and Cl with Esters

✍ Scribed by Peng Liang ; Yujing Mu; Véronique Daële; Abdelwahid Mellouki

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
295 KB
Volume
11
Category
Article
ISSN
1439-4235

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✍ Tomasz Gierczak; James B. Burkholder; A. R. Ravishankara 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 160 KB

## Abstract Rate coefficients are reported for the gas phase reaction of OH with OClO over the temperature range 242–392 K at 25, 50, and 100 Torr (He). Kinetic measurements were made using pulsed laser photolysis with laser induced fluorescence detection of the OH radical. The measured rate coeffi

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✍ M. K. Gilles; J. B. Burkholder; A. R. Ravishankara 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 159 KB 👁 1 views

Rate coefficients for the reaction of OH with Cl 2 , (k 1 ), Br 2 , (k 2 ) and I 2 , (k 3 ), were measured under pseudo-first-order conditions in OH. OH was produced by pulsed laser photolysis of H 2 O 2 (or HNO 3 ) and its temporal profile was monitored by laser-induced fluorescence. The measured r

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## Abstract The relative‐rate method has been used to determine the rate coefficients for the reactions of OH radicals with three C~5~ biogenic alcohols, 2‐methyl‐3‐buten‐2‐ol (__k__~1~), 3‐methyl‐3‐buten‐1‐ol (__k__~2~), and 3‐methyl‐2‐buten‐1‐ol (__k__~3~), in the gas phase. OH radicals were prod

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An error was discovered in the method used for calculating the moments of inertia for the internal rotations in the activated complex. In order to retain good agreement between theory and experiment, it was necessary to change some other molecular parameters of the activated complex. The following c