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Rate Coefficients for Intramolecular Homolytic Substitution of Oxyacyl Radicals at Sulfur

✍ Scribed by Aitken, Heather M.; Horvat, Sonia M.; Coote, Michelle L.; Lin, Ching Yeh; Schiesser, Carl H.

Book ID
120065349
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
2013
Tongue
English
Weight
767 KB
Volume
66
Category
Article
ISSN
0004-9425

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Rate coefficients for intramolecular hom
Rate coefficients for intramolecular homolytic substitution of oxyacyl radicals at selenium
✍ Heather M. Aitken; Sonia M. Horvat; Carl H. Schiesser; Ching Yeh Lin; Michelle L πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 365 KB

## Abstract Ab initio and density functional calculations predict that intramolecular homolytic substitution reactions of oxyacyl radicals at the selenium atom in ω‐alkylseleno‐substituted radicals proceed via mechanisms that do not involve hypervalent intermediates. When the leaving radical is __t