𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Rate coefficient for the reaction: Br+Br2O→Br2+BrO

✍ Scribed by James B. Burkholder

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
140 KB
Volume
30
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

The room temperature rate coefficient for the reaction (3) Br ϩ Br O : Br ϩ BrO 2 2 has been measured using the technique of pulse-laser photolysis with long-path transient absorption detection of the BrO reaction product. A value of k ϭ (2.0 Ϯ 0.5) ϫ 3 was determined. The photolysis products of Br 2 O at were Ϫ10 3 Ϫ1 Ϫ1

10 cm molecule s 308 nm also examined.

📜 SIMILAR VOLUMES

Rate constant for the reaction BrO + NO
Rate constant for the reaction BrO + NO → Br + NO2
✍ Ming-Taun Leu 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 358 KB

The rate constant for the reaction BrO + NO -+ Br f NO2 has been determine4 over the tempemture range 230 I( to 425 K in a discharge flow system using a mass spectrometer as a detector\_ Results, expressed in the Arrhenius form kr = (7.11 5 0.23) X 10-t\* eup[(296 f 10)/T] cm3 s-t, are compared with

Rate constant for the reaction Br + O3 →
Rate constant for the reaction Br + O3 → BrO + O2 from 248 to 418 K: Kinetics and mechanism
✍ Darin W. Toohey; Wm. H. Brune; J. G. Anderson 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 701 KB

The rate constant for the Br + O3 -+ BrO + O2 reaction was measured by the discharge flow technique, employing resonance fluorescence detection of Br. Over the temperature range 248 to 418 K, in 1 to 3 torr of He, decays of Br in excess 0, yield the value k , = (3.28 -+ 0 . 40) x 10-'1e'~944'30''T c

Absolute rate constant for the reaction
Absolute rate constant for the reaction OH + HBr → H2O + Br
✍ A.R. Ravishankara; P.H. Wine; A.O. Langford 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 519 KB

The technique of her flash photolysis-resonance fhorescence has been employed to study the kinetics of the reaction OH + HI+ -Hz0 + Br over the temperature ranse 249-416 K\_ The rate conshnt is found to be independent of tcmpera-hue\_ A simple aberage of the results obtained at six temperatures give

Kinetic study of the reactions Br + IBr→
Kinetic study of the reactions Br + IBr→I + Br2 and I + Br2→Br + IBr
✍ Y. Bedjanian; G. le Bras; G. Poulet 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 174 KB 👁 2 views

The kinetics of the title reactions have been studied using the discharge-flow mass spectrometic method at 296 K and 1 torr of helium. The rate constant obtained for the forward reaction (1), using three different experimental approaches (kinetics of Br Br ϩ IBr : I ϩ Br 2 consumption in excess of

Rate coefficients for the reactions CH3
Rate coefficients for the reactions CH3 + Br2 (224–358 K), CH3CO + Br2 (228 and 298 K), and Cl + Br2 (228 and 298 K)
✍ V. Khamaganov; J. N. Crowley 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 576 KB

## Abstract Rate coefficients for the reactions of CH~3~ + Br~2~ (__k__~2~), CH~3~CO + Br~2~ (__k__~3~), and Cl + Br~2~ (__k__~5~) were measured using the laser‐pulsed photolysis method combined with detection of the product Br atoms using resonance fluorescence. For the reactions involving organic