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Rate coefficient calculations on the three-dimensional D + HCl → DCl + H reaction using a new quantum-dynamical approximation

✍ Scribed by D.C. Clary


Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
415 KB
Volume
80
Category
Article
ISSN
0009-2614

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✦ Synopsis


Rate coefficient calculations for the three-dimensional D + HCI -DC1 + H reaction are reported. A new quantum method is used, which involves applying the energy sudden approximation to the entrance channel and the centrifugal sudden approximation to the exit channel. Good agreement with quasiclassical results is obtined