Raspailynes, Novel Long-Chain Acetylenic Enol Ethers of Glycerol from the Marine Sponges Raspailia pumila and Raspailia ramosa

✍ Scribed by Graziano Guella; Ines Mancini; Francesco Pietra

• Publisher: John Wiley and Sons
• Year: 1987
• Tongue: German
• Weight: 753 KB
• Volume: 70
• Category: Article
• ISSN: 0018-019X
• DOI: 10.1002/hlca.19870700417

✦ Synopsis

We loosely use here the term 'higher polarity' to mean a higher retention time on silica-gel chromatography. For convenience, id1 raspailynes and derivatives thereof are numbered as shown in the Formulae 1-14 Systematic names are given in the Summary and Exper. Part.

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Likely, the absolute configuration of the raspailynes could have otherwise been determined by Snatzke's circular dichroic method in the presence of the Mo2(O2CCH,), complex . We thank Prof. G. Snatzke for suggesting us this possibility.