## Abstract Complete thf donor exchange is observed when complexes Ln[N(SiHMe~2~)~2~]~3~(thf)~2~ (Ln = La, Nd) are treated with the monofunctional donor molecules triphenylphosphane oxide, __N__‐methylimidazole, and 1,3‐dimethylimidazolin‐2‐ylidene. The resulting complexes Ln[N(SiHMe~2~)~2~]~3~(don
✦ LIBER ✦
Rare-Earth Metal Bis(dimethylsilyl)amide Complexes Supported by Cyclooctatetraenyl Ligands
✍ Scribed by Christian Meermann; Kouji Ohno; Karl W. Törnroos; Kazushi Mashima; Reiner Anwander
- Book ID
- 102827739
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 900 KB
- Volume
- 2009
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The reactions of anhydrous LnCl~3~ (Ln = Y, Nd, Sm, Lu) with two equiv. of sodium __N__,__N′__‐dicyclohexyl‐__N′′__‐bis(trimethylsilyl)guanidinate Na[(Me~3~Si)~2~NC(NCy)~2~], obtained from Na[N(SiMe~3~)~2~] and the 1,3‐dicyclohexyl‐substituted carbodiimide CyN=C=NCy in THF, yield the mo
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