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Rare earth complexes of phenoxy-thioether ligands: synthesis and reactivity in the ring opening polymerization of cyclic esters

✍ Scribed by Mazzeo, Mina; Tramontano, Roberta; Lamberti, Marina; Pilone, Alessia; Milione, Stefano; Pellecchia, Claudio

Book ID
120050752
Publisher
Royal Society of Chemistry
Year
2013
Tongue
English
Weight
828 KB
Volume
42
Category
Article
ISSN
1477-9226

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πŸ“œ SIMILAR VOLUMES

Ring-opening polymerization of six-membe
Ring-opening polymerization of six-membered cyclic esters catalyzed by tetrahydroborate complexes of rare earth metals
✍ Yuushou Nakayama; Kenta Sasaki; Naoki Watanabe; Zhengguo Cai; Takeshi Shiono πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 English βš– 341 KB

Catalytic behavior of tetrahydroborate complexes of rare earth metals, Ln(BH 4 ) 3 (THF) x (1: ), for ring-opening polymerization (ROP) of six-membered cyclic esters, d-valerolactone (VL) and D,L-lactide (D,L-LA), was studied. The controlled polymerization of VL with 1-6 proceeded in THF at 60 C. T