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Rapid synthesis of oligosaccharide moieties of globotriaosylceramide using fluorous protective group

✍ Scribed by Tsuyoshi Miura; Toshiyuki Inazu

Book ID: 104253031
Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 214 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)00091-1

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✦ Synopsis

The use of the Bfp (bisfluorous chain type propanoyl) group as a fluorous protective group made it possible to rapidly synthesize galabiose and the Gb3 oligosaccharide derivatives by a simple fluorous-organic extraction purification. The fluorous oligosaccharide synthesis using the Bfp group is an excellent strategic alternative to solid phase oligosaccharide synthesis, and removes some of the disadvantages of the solid phase method.

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