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Rapid protonic exchange and proton solvation in hydrazine and methyl-substituted hydrazines

✍ Scribed by G. V. Lagodzinskaya; N. G. Yunda; G. B. Manelis

Book ID: 112445773
Publisher: Springer
Year: 1981
Tongue: English
Weight: 580 KB
Volume: 30
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf00955271

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## Abstract The rates of NHCOOH proton exchange between 5‐amino‐(**1a**) and 5‐__N__‐methylamino‐(**1b**)3‐[2‐(5′‐nitro‐2′‐furyl)vinyl]‐1,2,4‐oxadiazoles and trifluoroacetic acid (TFA) have been measured by NMR spectroscopy. The values of the first‐order rate constant and thermodynamic parameters