Rapid method for combined X—{1H} NOE and T1 measurement using heteronuclear polarization transfer

✍ Scribed by Katalin E. Kövér; Péter Forgó; Gyula Batta

• Publisher: John Wiley and Sons
• Year: 1995
• Tongue: English
• Weight: 325 KB
• Volume: 33
• Category: Article
• ISSN: 0749-1581
• DOI: 10.1002/mrc.1260331105

✦ Synopsis

Abstract

A polarization transfer enhanced inversion‐recovery experiment is proposed for the combined measurement of heteronuclear T~1~ and NOE of low‐γ nuclei. This method offers significant time savings compared with conventional relaxation measurements. The reliability and accuracy of the combined T~1~, and NOE determination and its dependence on the experimental set‐up is also demonstrated. The proposed approach may be preferred for multiple field/multiple temperature model‐free analysis of molecular dynamics.