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Rapid interspecies energy flow between vibrationally excited SF6 and the asymmetric stretch of N2O

✍ Scribed by Asghar Fakhr; Richard D. Bates Jr.


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
539 KB
Volume
71
Category
Article
ISSN
0009-2614

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✦ Synopsis


Rapld, selective colhsion-dependent excitation of NzO following pumping of SF6 with a CO2 laser is reported. The NzO fluorescence nse depends on the pressure of each component and is dominated by the SFe-dependent contribution of 2290 ms-t To& _ The subsequent fall is governed by V +V processes among SF6 viirational modes. * Ambartzumian and Doyennette [9] report privately having seen very rapid sensituation in SF6 -NH3 and CO1 -HBr mixtures respectively similar to the processes studied in detail for SFe-NzO