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Rapid, General Access to Chiral β-Fluoroamines and β,β-Difluoroamines via Organocatalysis

✍ Scribed by Fadeyi, Olugbeminiyi O.; Lindsley, Craig W.

Book ID
126981676
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
138 KB
Volume
11
Category
Article
ISSN
1523-7060

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✍ Xiu-Fang Cao; Ming Hu; Fei Li; Wen-Chang Lu; Guang-Ao Yu; Sheng-Hua Liu 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 German ⚖ 154 KB

## Abstract magnified image A highly enantioselective approach towards the synthesis of __β__‐substituted chiral ketones by utilizing __Grignard__ reagents was achieved. The (__R__)‐ and (__S__)‐antipodes of the target chiral ketones **2a**–**2k** were obtained with up to 100% ee from chiral __N__