Rapid charge migration within 1,4-benzoquinone stacks in the solid phases of 2,5-Di-n-decoxy-1,4-benzoquinone

✍ Scribed by E. M. D. Keegstra; J. W. Zwikker; L. W. Jenneskens; P. G. Schouten; M. P. de Haas; J. M. Warman; A. Schouten; H. Kooijman; A. L. Spek

• Publisher: Elsevier Science
• Year: 2010
• Tongue: English
• Weight: 182 KB
• Volume: 112
• Category: Article
• ISSN: 0165-0513
• DOI: 10.1002/recl.19931120620

✦ Synopsis

Abstract

Temperature dependent, radiation‐induced conductivity measurements of 2,5‐di‐n‐decoxy‐1,4‐benzoquinone (1) unambiguously show that self‐assembly of the 1,4‐benzoquinone moieties into stacks is a prerequisite for rapid electron and/or hole migration.