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Rapid access to tungsten-183 NMR parameters of tungsten complexes via reverse 2D proton-tungsten-183 and phosphorus-31-tungsten-183 NMR spectroscopy

✍ Scribed by Benn, Reinhard; Brenneke, Herbert; Heck, Juergen; Rufinska, Anna


Book ID
126131062
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
453 KB
Volume
26
Category
Article
ISSN
0020-1669

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## Abstract 2D^1^H NOESY and inverse detected ^183^W NMR measurements for the pseudo‐octahedral Ξ·^3^‐allyl complexes W(CO)~2~(Tpβ€²)(Ξ·^3^‐CH~2~CHCDPh) (1) and W(CO)~2~(Tpβ€²)(Ξ·^3^‐CH~2~CHCHCH~3~) (2), where Tpβ€² = hydridotris(3,5‐dimethylpyrazolyl)borate are reported. The observed solution structure for

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