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Random Copolymerization of Norbornene with Higher 1-Alkene with ansa -Fluorenylamidodimethyltitanium Catalyst

✍ Scribed by Shiono, Takeshi; Sugimoto, Mitsunori; Hasan, Tariqul; Cai, Zhengguo; Ikeda, Tomiki


Book ID
125968561
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
192 KB
Volume
41
Category
Article
ISSN
0024-9297

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πŸ“œ SIMILAR VOLUMES


Highly Active Syndiospecific Living Poly
✍ Zhengguo Cai; Masayoshi Ohmagari; Yuushou Nakayama; Takeshi Shiono πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 213 KB

## Abstract 1‐Hexene polymerization was conducted by [__t__‐BuNSiMe~2~(3,6‐__t__‐Bu~2~Flu)]TiMe~2~ (**1**) using trialkylaluminum‐free modified methylaluminoxane (dMMAO) as a cocatalyst in toluene. The system produced living syndiotactic poly(1‐hexene) with high turnover frequency of propagation (T