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Random coil dimensions of poly(1-hexadecene)

✍ Scribed by Begoña Peña; Marcelo Aroca; Ernesto Pérez; Antonio Bello; Evaristo Riande; Rosario Benavente

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
458 KB
Volume
198
Category
Article
ISSN
1022-1352

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✦ Synopsis

Abstract

The characteristic ratios of three samples of poly(1‐hexadecene) with different tacticities were evaluated from intrinsic viscosity and molecular weight data obtained with a size exclusion chromatograph with dual (concentration plus viscosity) detector. No significant differences were found for the characteristic ratio in the studied range of tacticities. Theoretical calculations for the unperturbed dimensions were also performed for these samples by using the rotational isomeric state model, and compared with the experimental results.

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