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Raman study of (NH4)2CuCl4 · 2H2O. I. dynamics and structure in low temperature phase

✍ Scribed by M.L. Bansal; V.C. Sahni; A.P. Roy

Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
126 KB
Volume
27
Category
Article
ISSN
0038-1098

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Infrared evidence of a low-temperature transition in (NH4)2CuCl)4·2H2O
✍ Ian A. Oxton; Osvald Knop 📂 Article 📅 1977 🏛 Elsevier Science 🌐 English ⚖ 285 KB

Infrared spectra of the isotopically dilute HDO and NHsD+ species in (NH~)~CUC~J-~H~O are interpreted as revealing the presence of three phases which exist between room and liquid-helium temperatures. The transiticn between phases II and III appears to be of the order-disorder type. Recently [l] we