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Raman studies of the isotopic effect in solid and matrix-isolated oxygen

✍ Scribed by A. Kornath; I. Köper

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
171 KB
Volume
28
Category
Article
ISSN
0377-0486

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✦ Synopsis

The Raman spectra of oxygen with di †erent isotope compositions were investigated in the solid state and in argon and nitrogen matrices at 15 K. The fundamental vibration of the isotopomers 16O17O, 16O18O and 17O17O reveal a doublet of lines, each separated by 2.2 cm-1, in solid oxygen and in nitrogen matrices. The isotopic e †ect is independent of isotope composition and can be annealed by a warm-up cycle. 1997

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