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Raman spectrum modification in the presence of solvated electrons. Observation by polarization CARS

✍ Scribed by S.A. Akhmanov; L.S. Aslanyan; A.F. Bunkin; T.S. Zhuravleva; A.V. Vannikov

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
393 KB
Volume
66
Category
Article
ISSN
0009-2614

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✦ Synopsis

Ging the method of polurnation CARS, modification of the bant contour of the solvent molecnles (hexamethylphosphortriamide, HVP'1) was observed in the presence of the solvated electron (e). The effect is only just observable for C-H sbration modes. Spectral parameters of the band due to the interaction of es and solvent molecules uere determined by numerical fitting. Some conclusions concernms the nature of (\mathrm{e}_{s}) in HMPd were drasn.

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Observation of saturation broadening of
Observation of saturation broadening of the coherent anti-stokes raman spectrum (cars) of acetylene in a pulsed molecular beam
✍ M.D. Duncan; P. Oesterun; F. KΓΆnig; Robert L. Byer πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 English βš– 313 KB

Reported is the fust observation of saturation broadening in a high-resoiution coherent Raman spectrum of the "2 Qbranch of acetylene The measured saturation broadening of 1050 MHz is significantly greater than the ulculatcd nc Stark broadening of less than 100 MHz.