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Raman spectrum and vibrational assignments for tricyclo(3.3.0.02,6) octane

✍ Scribed by Frank G. Baglin; Garry N. Fickes

Publisher
John Wiley and Sons
Year
1976
Tongue
English
Weight
268 KB
Volume
5
Category
Article
ISSN
0377-0486

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πŸ“œ SIMILAR VOLUMES

The conformation and configurational ass
The conformation and configurational assignment of 6,7-disubstituted 2-oxabicyclo[3.3.0]octan-3-ones
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## Abstract The conformational behaviour of 6‐alkyl‐3‐oxo‐2‐oxabicyclo[3.3.0]octan‐7‐ols and some derivatives possessing the configurations a (6‐__endo__‐7‐__exo__), b (6‐__endo__‐7‐__endo__) and c (6‐__exo__‐7‐__endo__) is discussed. It is shown that an easy configurational assignment is possible

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## Abstract Three‐step syntheses and the resolution into the enantiomers are reported for the tricyclo[3.3.0.0^2,8^]octan‐3‐ones **7–9**, which are destined to serve as synthons for polycyclopentanoid terpenes and prostacyclin analogs. Routine overall yields of __ca.__ 75% for **7**, 40% for **8**,