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Raman Spectroscopy of Short-Lived Terthiophene Radical Cations Generated by Photochemical and Chemical Oxidation

✍ Scribed by Tracey M. Clarke; Keith C. Gordon; Wing Sum Chan; David Lee Phillips; Pawel Wagner; David L. Officer


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
343 KB
Volume
7
Category
Article
ISSN
1439-4235

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Free radical studies by resonance Raman
✍ E. E. Ernstbrunner; R. B. Girling; W. E. L. Grossman; E. Mayer; K. P. J. William 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 English ⚖ 654 KB

## Abstract The free radical cation of 1,4‐diaminobenzene (__p__‐phenylenediamine, PPD^+.^) has been generated in aqueous solution, wherein it is short‐lived, by oxidation of the parent compound with bromine. The same PPD^+.^ radical has also been produced by UV photolysis of the parent at 77 K in