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Raman spectroscopic study on the enthalpy of conformational change of N,N-dimethylpropionamide bound to calcium ion

✍ Scribed by Yasuhiro Umebayashi; Yutaka Mune; Taiga Tsukamoto; Yue Zhang; Shin-chi Ishiguro


Book ID
103835540
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
325 KB
Volume
118
Category
Article
ISSN
0167-7322

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The interaction of Mg2+, Ca2+, Zn2+, and Cd2' with calf thymus DNA has been investigated by Raman spectroscopy. These spectra reveal that all of these ions, and particularly Zn2+, bind to phosphate groups of DNA, causing a slight structural change in the polynucleotide at very small metal : D N A (