Molecular structures of the two tautomers of a β€-diketone 1-phenyl-3-methyl-4-benzoyl-5pyrazolone (PMBP) were studied by MS, UV, IR, and X-ray diffraction methods. The mass spectra show little difference for the two forms of PMBP, while there are notable differences in the IR spectra as KBr pellets
Raman spectroscopic study on keto-enol tautomers of 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone
β Scribed by Y. Akama; A. Tong; N. Matsumoto; T. Ikeda; S. Tanaka
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 205 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0924-2031
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π SIMILAR VOLUMES
The broad infrared bands of the polymorphic crystals of I-phenyl-3-methyl-4-benzoyl+pyrazolone (PMBP) were assigned unequivocally by examining the IR spectra of solutions and Raman spectra. The strong band at 2550 cm-' of a colourless crystal was attributed to an intermolecular hydrogen bond NH...O=
The scandium complexes of Sc(PMBP) 3 $H 2 O (non-crystal) and Sc(PMBP) 3 (crystal) with 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone (PMBP) were prepared and characterized by thermal analysis, IR, NMR and MS spectroscopies. The crystal structure of the complex, obtained by X-ray analysis, indicates that