𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Raman spectroscopic study of hydrogen bonding of poly(N-vinyl-2-pyrrolidone) in heavy water and dimethyl sulfoxide

✍ Scribed by Naoki Tanaka; Kensaku Ito; Hiromi Kitano

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
555 KB
Volume
195
Category
Article
ISSN
1022-1352

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The Raman spectra of solutions of poly(N‐vinyl‐2‐pyrrolidone) (PVP; M̄~w~ = 1 000, 10 000, 40 000 and 360 000) in D~2~O and dimethyl sulfoxide (DMSO) were measured at various concentrations. PVP is hydrated by D~2~O in a manner different from N‐ethyl‐2‐pyrrolidone (NEP) and N‐methyl‐2‐pyrrolidone (NMP), monomer analogues of PVP. The self‐association of DMSO molecules in the solution of PVP was found to be different from that in the solution of NMP by using difference spectroscopy. These phenomena were attributed to a net‐like structure of concentrated solutions of PVP.

📜 SIMILAR VOLUMES

Graft copolymerization of n-vinyl-2-pyrr
Graft copolymerization of n-vinyl-2-pyrrolidone on dimethyl sulfoxide pretreated poly(ethylene terephthalate) films using azobisisobutyronitrile initiator
✍ Halil İbrahim Ünal; Ramazan Coşkun; Oya Şanli; Mustafa Yiğitoğlu 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 192 KB 👁 2 views

Poly(ethylene terephthalate) (PET) films were grafted with n-vinyl-2-pyrrolidone ( n-VP) using an azobisisobutyronitrile (AIBN) initiator. Films were pretreated in dimethyl sulfoxide (DMSO) for 1 h at 140ЊC before the polymerization reaction was carried out. Variations of graft yield with time, temp

Hydrogen Bonding Interaction and Miscibi
Hydrogen Bonding Interaction and Miscibilization of Ternary Blends of Poly(2-vinylpyridine), Poly(N-vinyl-2-pyrrolidone), and 4,4′-(1,4-Phenylenediisopropylidene)bisphenol
✍ Xue-Dong Li; Suat H. Goh 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 291 KB

## Abstract The interaction energy densities of poly(2‐vinylpyridine) (P2VPy)/4,4′‐(1,4‐phenylenediisopropylidene)bisphenol (PDIPBP) blend and poly(__N__‐vinyl‐2‐pyrrolidone) (PVP)/PDIPBP blend were determined using melting point depression method. The interaction between PVP and PDIPBP is stronger

Viscosity Behaviour of Poly(N-vinyl-2-py
Viscosity Behaviour of Poly(N-vinyl-2-pyrrolidone) in a Water/VOSO4Binary Mixture: Preferential Interactions
✍ Lozano, M.; Blanco, M. D.; Olmo, R.; Lozano, R.; Teijón, J. M. 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 256 KB 👁 2 views

Poly(N-vinyl-2-pyrrolidone) (PVP) [2]/water [3] ternary [1]/VOSO 4 system interactions have been studied by viscometric and densitometric techniques. Preferential water absorption inside the macromolecular coil and preferential salt interaction with the polymer external domain were observed. The unp