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Raman Spectroscopic Studies on SOF2in Argon Matrices. 1. Molecular Dynamics in Matrices

✍ Scribed by Andreas Kornath; Nina Hartfeld

Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 125 KB
Volume: 183
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1997.7267

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✦ Synopsis

The vibrational fine structure of SOF 2 has been studied in the solid state (80 K, 15 K) and in argon matrices (M/S Å 30, 100, 250, 500, 1000) by Raman spectroscopy. The splitting of the vibrations at the solid state and in low diluted argon matrices reflect the interactions between the SOF 2 molecules. The influence of annealing procedures at different dilution ratios with respect to the formation of van der Waals oligomers is discussed.

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