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Raman-spectroscopic investigations of ion—solvent interactions in concentrated solutions of LiCl in formic acid

✍ Scribed by B.M. Rode

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
536 KB
Volume
32
Category
Article
ISSN
0009-2614

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✦ Synopsis

%&spectra.of concentrated solutions of-LiCl.in HCOhtii'co&initig m&y ion pa&s and single solvated ions prove, .' .,-. 1-y.. to be sgi@bIe fir,ip afiproximate exj+montal estimation of,the &flue&e of th&& on the HCOOH malecule. Remukable '. : '. I.., &anger in thk C=O,_&6.and G'zf bonds of the solvent moiecul~ due to this in[luence ar&.observkd. These 6b&&ns

.'a$ sho)vn to b&in good ogkeken't !vkl calculated frequen.cy shifts, obt.ain:d 6~' semiempiri~l,molecuiar orbital methods -nppliecJ tb stiple,solvation models.

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