## Abstract Lithium perchlorate solutions in acrylonitrile (propenenitrile), in a range of concentration between 1 and 6 molal, were studied by using Fourier transform Raman spectroscopy. The new band in the __v__(CN) region proceeding from the bound species Li^+^β¦ (acrylonitrile)~__n__~ and the mo
Raman spectral studies of molten lithium nitrate-lithium perchlorate mixtures
β Scribed by M.H. Brooker; A.S. Quist; G.E. Boyd
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 534 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The Ratnan spectra of molten LiN03, LiClO.+ and mixtures of the two salts are reported. All bands appear tc arise from highly localized vibrational modes. The opectral features of molten LiNO3 can be accounted for by the hppothesis that two non-equivalent environments ara available to the nitrate ion.
π SIMILAR VOLUMES
The interdiffusion coefficient of thallous ion in molten lithium nitrate has heen measured by wave-front-shearing interferometry. The results are obtained in a region of low Tl+ concentration and can be summarized with an Arrhenius equation D = (3.95 & 1.14) x IO-' exp{-(6780 & 330)/RT}, (262-354"C)