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Raman spectra of pyridine adsorbed at a silver electrode

โœ Scribed by M. Fleischmann; P.J. Hendra; A.J. McQuillan

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
329 KB
Volume
26
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Raman spectroscopy has been employed for the first time to study the role of adsorption at electrodes. It has been possible to distinguish two types of pyridine adsorption at a silver electrode. The variation in intensity and frequency of some of the bands with potential in the region of the point of zero charge has given further evidence as to the structure of the electrical double layer; it is shown that the interaction of adsorbed pyridine and water must be taken into account.

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