Raman spectra of pyrazine resonant to the S2(π,π*) state and the geometry in excited state
✍ Scribed by I. Suzuka; Y. Udagawa; M. Ito
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 286 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Raman spectra resonant to the S 2 ( X,X*) state of pyrszine vapor consist of fundamentals. overtones and combinations of only two totally symmetric vibrations, vI and vaa_ Combining the Raman %ith tile absorption spectra it is euperimentaily verified that the molecular deformation upon e.ucitation is reflected on the resonamze Raman spectral _ Introduction Vibronic expansion combined with the Kramers-Heisenberg dispersion equation was successfully applied for the understanding of Raman intensity by several authors and conveniently reviewed by Tang and Albrecht [ 1] _ The most valuable feature of the vibronic theory of Raman intensity lies in that it has revealed the relationship between the Raman intensity and the
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