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Raman spectra and phase transition of ammonium uranyl nitrate

✍ Scribed by C. Caville


Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
254 KB
Volume
6
Category
Article
ISSN
0377-0486

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✦ Synopsis


Abstract

Raman spectra of single crystals of NH~4~UO~2~(NO~3~)~3~ are recorded for the temperature range 293–6 K. In various orientations the room temperature spectra are similar to the corresponding isomorphous rubidium and caesium salts. As the crystal is cooled the changes in the Raman spectra indicate a phase transition due to an ordering of the ammonium ions.


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