Raman spectra and phase transition of ammonium uranyl nitrate
β Scribed by C. Caville
- Publisher
- John Wiley and Sons
- Year
- 1977
- Tongue
- English
- Weight
- 254 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0377-0486
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β¦ Synopsis
Abstract
Raman spectra of single crystals of NH~4~UO~2~(NO~3~)~3~ are recorded for the temperature range 293β6 K. In various orientations the room temperature spectra are similar to the corresponding isomorphous rubidium and caesium salts. As the crystal is cooled the changes in the Raman spectra indicate a phase transition due to an ordering of the ammonium ions.
π SIMILAR VOLUMES
A comparative study of the infrared and Raman spectra of L-valine nitrate and L-leucine nitrate helps in determining the role of hydrogen bonds in these crystals. Both compounds have carboxylic and protonated amino groups in the cation while the nitrate ion forms the anion. The wavenumbers of severa