Raman linewidth study of intermolecular interactions of methanol in aqueous solution

✍ Scribed by Kazutoshi Tanabe; Seiji Tsuzuki

• Publisher: Elsevier Science
• Year: 1986
• Tongue: English
• Weight: 348 KB
• Volume: 42
• Category: Article
• ISSN: 1386-1425
• DOI: 10.1016/0584-8539(86)80143-x

✦ Synopsis

Isotrops Raman linewidths of the C-H and C-D symmetric stretchmg modes of methanol and methanol-d4 have been measured as a function of concentration m normal water, m heavy water and m carbon tetrachlonde On the basis of the concentration dependence of observed hnewidths, mtermolecular mteractions and hqmd structures m the methanol-water system are discussed It IS suggested that there may be some difference m mutual affimties or abditles ofhydrogen bonding m the order D20 > Hz0 > CD,OD > CHsOH