Raman Intensity Study of the VC=O Band of Cyclohexanone Complexed with Phenol Derivatives
✍ Scribed by C. Thijs; T. H. Zeegers-Huyskens
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 296 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0037-9646
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The formation enthalpy, the frequency shift and integrated intensity of the '.'OH stretching vihration have heen determined for hydrogen bonded complexes formed between phenol derivatives and tetramethylthiourea or dimethylthioformamide. These data are compared with comnlexes involving carhonyl hase
## Abstract Dinuclear complexes [L~2~Fe^III^~2~] (1), [L~2~Mn^III^~2~] (2a), [L~2~Mn^III^~2~(THF)~2~] (2b), [L~2~Cr^III^~2~] (3), [L(V^IV^O)~2~(OCHMe~2~)] (4) and [L~2~(V^V^O)~2~] (5) with a pentadentate phenol‐containing ligand H~3~L (= C~6~H~2~(CH~3~)(OH){[C(CH~3~)~3~]~2~(OH)NCH}~2~) bearing the