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Raman intensity of lattice vibrations in BaCl2 · 2H2O. Many-body treatment

✍ Scribed by Isao Kanesaka; Toshiyuki Matsuda; Yukie Niwa

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
369 KB
Volume
25
Category
Article
ISSN
0377-0486

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✦ Synopsis

Abstract

Polarized Raman spectra of BaCl~2~ · 2H~2~O and their assignments are reported. The Raman intensity was analysed by means of the pair approximation and the many‐body interaction among induced dipoles. It was found that the many‐body treatment is more quantitative than the pair approximation, although the agreement between the observed and calculated polarized spectra is still incomplete. The difference between the two methods is discussed.

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