Raman and infrared study of (PbO)x(P2O5)(1−x) glasses
✍ Scribed by Gwenn Le Saoût; Patrick Simon; Franck Fayon; Annie Blin; Yann Vaills
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 388 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0377-0486
- DOI
- 10.1002/jrs.911
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Amorphous V205 can be obtained by cooling from the melt. This amorphous oxide is very sensitive to water vapour and can even be dissolved in water to give a vanadium pentoxide gel. The hydration process has been followed by infrared and Raman spectroscopy between 20 and 4000 cm-l. Short-range order
An e.m.f. study of {xNa2O + (1 -x)P2O5}(l) containing x = 0.43 to 0.75 has been carried out over the temperature range 750 K to 1300 K. The set of thermodynamic properties, both partial and integral, is obtained. Significant negative deviations from ideal behaviour of DfGm and DfHm are observed. The