Raman and infrared studies supported by ab initio calculations for the determination of conformational stability, silyl rotational barrier and structural parameters of cyclohexyl silane
β Scribed by Chao Zheng; Swaminathan Subramaniam; Victor F. Kalasinsky; James R. Durig
- Book ID
- 104058442
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 559 KB
- Volume
- 785
- Category
- Article
- ISSN
- 0022-2860
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π SIMILAR VOLUMES
The structural parameters and conformational stabilities of the trans (the CΓCl bond is trans to the phosphorus lone pair) and gauche rotamers of chloromethyldichlorophosphine, were obtained from ab initio cal-ClCH 2 PCl 2 , culations up to the MP2/6-311 + G\*\* level. In each case the gauche form w
## Abstract The Raman and infrared spectra (3500β50 cm^β1^) of the gas, liquid or solution, and solid were recorded of 2,2,3,3,3βpentafluoropropylamine (CF~3~CF~2~CH~2~NH~2~) and the ND~2~ isotopomer. Variable temperature (β55 to β 100 Β°C) studies of the infrared spectra (3600β400 cm^β1^) of sample