Raman and infrared spectra of solid tribromofluoromethane

✍ Scribed by N. M. Zakhary; S. A. Schlueter; A. Anderson

• Publisher: John Wiley and Sons
• Year: 1992
• Tongue: English
• Weight: 396 KB
• Volume: 23
• Category: Article
• ISSN: 0377-0486
• DOI: 10.1002/jrs.1250231206

✦ Synopsis

Abstract

Vibrational spectra of solid tribromofluoromethane at temperatures between 12 K and the melting point were obtained using Raman and infrared techniques, with special emphasis on the lattice modes. No evidence for a solid‐state phase transition was found. Lattice peaks are tentatively assigned on the basis of geometrical and intensity arguments. It is shown that the spectra are compatible with a non‐centrosymmetric unit cell containing four molecules.