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RAFT-Mediated ab Initio Emulsion Copolymerization of 1,3-Butadiene with Acrylonitrile

✍ Scribed by Hlalele, Lebohang; D’hooge, Dagmar R.; Dürr, Christoph J.; Kaiser, Andreas; Brandau, Sven; Barner-Kowollik, Christopher

Book ID: 121860320
Publisher: American Chemical Society
Year: 2014
Tongue: English
Weight: 431 KB
Volume: 47
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma500055q

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## Abstract The transition structures of the hetero‐Diels‐Alder reaction of (__E__)‐ and (__Z__)‐1‐aza‐1,3‐butadiene (8 and 11) were studied by means of ab initio (UHF/6‐31+G\* and RHF/6‐31+G\*) and semiempirical (AM1, PM3) methods. The energy surface of the title reaction was calculated with AM1/C