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Radiometric ages of the Fire Clay tonstein [Pennsylvanian (Upper Carboniferous), Westphalian, Duckmantian]: A comparison of U–Pb zircon single-crystal ages and 40Ar/39Ar sanidine single-crystal plateau ages

✍ Scribed by Paul C. Lyons; T.E. Krogh; Y.Y. Kwok; Donald W. Davis; William F. Outerbridge; Howard T. Evans Jr.


Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
221 KB
Volume
67
Category
Article
ISSN
0166-5162

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✦ Synopsis


The Fire Clay tonstein [Pennsylvanian (Upper Carboniferous), Westphalian Series, Duckmantian Stage]-a kaolinized, volcanicash deposit occurring in Kentucky, West Virginia, Tennessee, and Virginia-is the most widespread bed in the Middle Pennsylvanian of the central Appalachian basin, USA. A concordant single-crystal U-Pb zircon datum for this tonstein gives a 206 Pb/ 238 U age of 314.6 ± 0.9 Ma (2σ). This age is in approximate agreement with a mean sanidine plateau age of 311.5 ± 1.3 Ma (1σ, n = 11) for the Fire Clay tonstein. The difference between the two ages may be due to bias between the 40 K and 238 U decay constants and other factors. The age of the Fire Clay tonstein has important implications for Duckmantian Stage (Westphalian Series) sedimentation rates, correlations with the Westphalian Series of Europe, Middle Pennsylvanian volcanic events, and the late Paleozoic time scale.