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Radiochemical investigation of polymer unsaturation. Reaction of butyl rubber with radiochlorine

✍ Scribed by I.C. McNeill

Book ID
103347149
Publisher
Elsevier Science
Year
1963
Tongue
English
Weight
543 KB
Volume
4
Category
Article
ISSN
0032-3861

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The kinetics of H abstraction by methyl and tert.butyl radicals from poly(p-tert.butyl styrene) (PTL3) films (5 Γ— 10 3 mm thick) have been investigated at 298 K, both radicals being produced from the polymer by its exposure to short-wave u.v. radiation (2 = 254 nm) at pressures < 10 -4 Pa. Different