✦ LIBER ✦
Radioactively labelled epoxides. part V. Tritium labelled K-region oxides and trans-dihydrodiols of pyrene, benzo[a]pyrene and dibenz[a, h]anthracene
✍ Scribed by Frans Setiabudi; Franz Oesch; Karl L. Platt
- Publisher
- John Wiley and Sons
- Year
- 1987
- Tongue
- French
- Weight
- 296 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0022-2135
No coin nor oath required. For personal study only.
✦ Synopsis
T r i t i u m l a b e l l e d K-region oxides o f pyrene, benzoCalpyrene and d i b e n z [ G ] a n t h r a c e n e have been prepared by c y c l i z a t i o n o f the corresponding t r a n s -d i h y d r o d i o l s which were obtained by r e d u c t i o n o f K-region quinones w i t h sodium b o r o t r i t i d e i n t h e presence o f oxygen. This s y n t h e t i c pathway n o t o n l y y i e l d s two m e t a b o l i c a l l y important r a d i o a c t i v e l y l a b e l l e d d e r i v a t i v e s o f p o l y c y c l i c aromat i c hydrocarbons i n a simple